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Over many weeks, I made many calls, inquiring about the energy that's burned away (wasted!) in the baking process and what benefits you get in return. Charcoal-briquet manufacturers in the United States couldn't furnish experts. The Department of Energy suggested I talk with someone in "fossil fuels." "Charcoal is not a fossil fuel," I sighed. "Oh, that's a fossil fuel," said the spokesman at the Environmental Protection Agency. "Charcoal is just old dinosaurs." "Charcoal," I mumbled, "is made from trees." Eventually, I stumbled across the Combustion Institute. |
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(Now, isn't that a place where every 12-year-old would like to work? "OK, kids. This morning, we're going to combust some Lincoln Logs. This afternoon, we're combusting Barbie's hair.") . |
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The Combustion Institute keeps tabs on professional combusters, and they recommended I talk to one
Dr. Robert Hurt at Brown University.
"What do you do at Brown?" I asked Dr. Hurt. "I'm a professor of charcoal," he snorted, cracking himself up. Actually, he works a fair amount with "activated charcoal," which is made from charcoal. He doesn't actually study the charcoal-making process, but he's an accomplished-enough combustor that he could describe the process and imagine its benefits. To make charcoal in a developing nation, you bake wood at a moderate temperature while it's buried under soil to deprive it of oxygen. (To make it in Missouri, where most of the domestic version is made, you use a more permanent oven.) This drives off the undesirable elements but keeps the carbon in the wood from burning. The undesirable elements are: Lots of water, which cools fire. It might take a year of outdoor drying to dry the wood naturally. Volatile compounds, like methane and hydrogen, also are sent packing. And tars, which is a generic name for big, smoky, sticky molecules that form liquids when they're cool, are sent away in reeking, yellow clouds. The tars, in particular, can contain carcinogenic compounds, like benzo-A-pyrene, and, according to Hurt's calculations, "a zillion" other bad actors. (This cooking process is messy. Missouri has historically exempted charcoal makers from some clean-air regulations, making it cheap to do business there. But laws in the making will require charcoal makers to clean up their act.) Anyway, with the volatile component baked "away," you're left with a heap of black stuff that's just 20- to 25-percent of the original volume of the wood. It's chiefly carbon, with traces of volatile chemicals and ash. And when it burns, it won't belch smoke, and it will burn long, hot and steady. So, charcoal is just wood with the messy and dangerous parts baked off. (Charcoal briquets are a little more than that -- they often have additives: borax to bind the charcoal; nitrate to ignite it; and lime to whiten the ash so you know to begin cooking.) |
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And solid stuff like carbon has a reputation for combusting with decorum. . |
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It's why you toast marshmallows over the coals of your campfire, not over the leaping, gassy
flames of the wood. Once the gasses are gone, the oxygen in the air around the coals is able
to come in and steadily pick off carbon atoms. These freshly-built molecules fly away as
carbon dioxide or, in trace amounts, carbon monoxide. These scorching-hot gases, Hurt says,
rise up and heat your marshmallow. And activated charcoal? The stuff in aquarium filters and drinking-water filters and air filters? If you let oxygen eat at charcoal a bit before extinguishing the flame, it bores countless tiny holes into the surface. These holes are marvelous at trapping molecules of filth from the water or air passing through. Activated charcoal is just burned charcoal, overcooked by amateur combusters who ignored that white ash on their briquets. |
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Hannah Holmes cooks up her campfire tales of quirky science from her home in Portland, Maine.
A fresh "Skinny On ...
" arrives here every other Friday, adding to her extensive work for Discovery Online. Hannah's writing also appears on the pages of
Escape, Outside, Sierra, Backpacker, Eco Traveler and Women's
Sports and Fitness. Send her a note at skinny@online.discovery.com.
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